Alkalinity in boiler water

Testing alkalinity in boiler water taylor technologies. Alkalinity is defined as the acid absorbing property of water. These are most commonly hydroxide oh, carbonate co 2, bicarbonate hco, phosphate po 3, and silicate sio 2. These metals corrosion rates are significantly reduced with higher ph waters. Alkalinity is a key control parameter for boilers outside of the prescribed operating range, it can lead to corrosion, caustic metal embrittlement, and carryover and cooling water systems where it has a significant effect on chemical treatments for scale and corrosion inhibition. Small amount of boiler water drawn off near surface continuously or intermittently function is to control concentration of dissolved solids. The conventional boiler water test finds only the presence of oh and half of co3. Keeping dissolved solids below the concentration that causes foaming requires continuous or periodic blowdown of the boiler. How does the total alkalinity come in boiler water.

Alkalinity of water means acid neutralization capacity of water. Phenolphthalein indicator a011 65ml dropper bottle. The p alkalinity in boiler water depend on the m alkanility of feed water. For this reason, alkalinity is an important part of a phosphate precipitation program. Napo4 can be used to adjust the alkalinity of boiler water. The water quality association defines alkalinity as the quantitative capacity of water to neutralize an acid. This can be achieved using carefully selected alkalinity builders designed specifically to control ph in boiler water systems. Increasing the boiler ph may reduce corrosion rates, allow the polymer to activate, and minimize silica scaling.

The precipitation and deposition of hardness salts in feed water to low pressure boilers is commonly a result of raising the feedwater temperature or the ph value. Waters with low alkalinity are very sensitive to changes in ph. Steam boiler rating and feed water temperature boiler output and feed water. Difference between p alkalinity and m alkalinity compare.

Boiler water treatment is used to control alkalinity, prevent scaling, correct ph, and to control conductivity. Depending upon the ph of the water, alkalinity can exist in water in three basic forms alkalinity relationships. It is also an important factor for assess the risk of corrosion in water cooling system and boiler, since the higher alkalinity suggested lower corrosivity in water chemistry. Steam thus produced can be used as a heating medium or as a working fluid in a prime mover, where it turns thermal energy to mechanical energy, which in turn may be converted to electrical energy. Alkalinity is a measurement of water s ability to neutralize acid. Cstn may 2006 w hether you are new to the water field or an old timer, alkalinity and ph relationships can still be confusing.

Jun 08, 2017 the major ions that contribute to the alkalinity of water are hydroxyl ions oh, carbonate ions co 3 2 and bicarbonate ions hco 3. Properly treat boiler water for efficient, long term. Boiler pressure psig tds alkalinity suspended solids silica 0 to 300 3500 700 300 125 301 to 450 3000 600 250 90 451 to 600 2500 500 150 50 601 to 750 2000 400 100 35 751 to 900 1500 300 60 20 901 to. Standard value of p alkalinity in boiler water is between 50300mg caco3l. Alkalinity test in natural waters, alkalinity is most commonly the result of bicarbonate and carbonate ions. If a boiler water possesses embrittling characteristics, steps must be taken to prevent attack of the boiler metal. Nov, 2018 the p alkalinity in boiler water depend on the m alkanility of feed water. The alkalinity acts as a ph buffer in coagulation and limesoda softening of water. Nov 29, 2012 a simple boiler is a closed vessel which is used for heating fluid, mainly water or converting it to steam. Apr 06, 2018 when testing boiler water, it is important to understand what you are testing for. P alkalinity the p alkalinity is a measure of the amount of acid required to drop the ph to approximately 8. Some levels of alkalinity content are required in boiler water, so the complete removal of alkalinity in the boiler is rare to be performed except in demineralization treatment.

Controlling ph ph is controlled by either removing water impurities or adding other chemicals to neutralize the condition. Alkalinity is categorized into three groups according to the end point given when an aqueous basic solution is titrated with an acid. Higher value of p alkalinity leads to scale formation and overheating of the inside of the boiler causing internal damage. Magnesium phosphate has a surface charge that can cause it to adhere to tube surfaces and then collect other solids.

The most appropriate boiler feed water treatment system will help the facility avoid costly plant downtime, expensive maintenance fees, and boiler failure as a result of scaling, corrosion, and fouling of the boiler and downstream equipment. Key difference p alkalinity vs m alkalinity the term alkalinity refers to the amount of an aqueous solution required to neutralize the acidity caused by an acid. Alkalinity builders boiler water treatment chemicals. Maximum flow velocities in water systems water velocities in pipes and tubes should not exceed certain limits. Inside the boiler the heat generates steam bubbles inside the water. Dealkalization alkalinity dealkalizers process water. What does the mean of malkalinity and p alkalinity in. Dealkalizers are most often used as pretreatment to a boiler and are usually preceded by a water softener. The presence of alkalinity in a water sample may be due to many different substances. It is also an important factor for assess the risk of corrosion in water cooling system and boiler, since the higher alkalinity suggested lower corrosivity in water.

Alkalinity control is part of the vecom marine fully coordinated treatment and should not be used in conjunction with a combined treatment. If you are in the market for an alkalinity increaser, the two most common are sodium bicarbonate nahco 3 and sodium carbonate na 2 co 3, more commonly known as soda ash. These problems can be overcome by proper, daily blowdown of the boiler. Alkalinity water treatment and alkalinity water filtration. In an emergency, increase the blow down rate if necessary to bring boiler water alkalinity under control. Aug 27, 2015 this video will cover information that you need to know about ph, alkalinity, and hardness, for your water treatment or water distribution exam. Boiler water conductivity measurement fundamentals. Alkalinity is a measure of the bicarbonate hco3, carbonate co3 and hydroxyl oh ions in the water.

Hardness in parts per million or grains per gallon. Alkalinity is a factor that most often dictates the amount of boiler blowdown. What is a boiler feed water treatment system and how does it. The mild steel boiler tubes prefer higher ph waters. Boiler water chemistry properties of feed water explored. General guidelines to prevent corrosion and scaling in low pressure boilers are as follows. That oxygen comes out of solution as the water boils, and it can eat holes in the boiler, right at the boiler s waterline.

The advantages of using alkalinity is to increase your boiler ph may be. Magnesium chloride, like magnesium sulphate, is soluble in fresh water. Common causes of foaming are excessive solids or alkalinity, and the presence of organic matter such as oil. Nalfleet alkalinity control provides alkaline conditions in the boiler water for optimum control of corrosion and scale deposition and should be used as part of a multiproduct treatment programme. Hydroxide alkalinity in order to accomplish three things. When testing boiler water, a conductivity meter is used to measure. In conclusion, alkalinity of water is very important parameter in boiler water treatment program. The alkalinity of boiler water should be sufficiently high enough to protect shell and plates against acidic corrosion, but not high enough to produce carryover.

Sodium nitrate is a standard treatment for inhibiting embrittlement in lowerpressure boiler systems. In boiler water, treatment specialists must maintain m or t. Composer alkalinity water are bicarbonate anion hco 3, carbonate co 3 2 and hydroxide oh. Maintaining alkalinity and ph of boiler water youtube. Alkalinity down products will be an acid like muriatic. Alkalinity in boiler water may be due to calcium, sodium, or magnesium.

P alkalinity is the measurement of hydroxide oh and carbonate ion. Based on alkalinity analysis we can predict the presence of free caustic as mentioned in above table. There can be too much conductivity in the feed water. The composition of boiler feed water must be such that the impurities in it can be concentrated a reasonable number of times inside the boiler, without exceeding the tolerance limits of the particular boiler design. Generally, natural water supplies have bicarbonate alkalinity, but no carbonate or hydroxide. Total alkalinity is measured by the amount, or concentration ppm in the water, not by how alkaline ph the water is. High boiler solids will lead to foaming, priming, surging and carry over. As a boiler generates steam, any impurities which are in the boiler feedwater and which do not boil off with the steam will concentrate in the boiler water. The total alkalinity of boiler water includes all dissolved components that are capable of reacting with acid. A boiler that makes up 4000 galday of water having 100 ppm of hardness, has a potential of accumulating over pounds of scale per year. Palkalinity is the measurement of hydroxide oh and carbonate ion co3 2 amount m alkanility is the measurement of hydroxide oh and bicarbonate hco3 and car. Bicarbonate is the most prevalent alkalinity in natural bodies of water. Sep 26, 2016 the most appropriate boiler feed water treatment system will help the facility avoid costly plant downtime, expensive maintenance fees, and boiler failure as a result of scaling, corrosion, and fouling of the boiler and downstream equipment. The later problem should be avoided by the use of alkalinity builders dosed into the hotwell or boiler shell.

Sodium hydroxide is the preferred approach, as the break. Jul 27, 2017 water is the most important liquid for sustained life because of its neutral ph of 7. Alkalinity is a key control parameter for boilers outside of the prescribed operating range, it can lead to corrosion, caustic metal embrittlement, and carryover and. Alkalinity is a measure of the bicarbonate hco3, carbonate co3. The boiler water needs to be alkaline and not acidic, so that it does not ruin the tubes. Most lowpressure boiler system operators monitor boiler water alkalinity because it correlates very closely with ph, while most feedwater, condensate, and highpressure boiler water requires direct monitoring of ph.

When testing boiler water, it is important to understand what you are testing for. Alkalinity is a standardized measure of the buffering capacity of water, that is, the quantitative capacity of bases in the water to neutralize acids. Depending upon the ph of the water, alkalinity can exist in water in three basic forms. There are 3 types of alkalinity, depending on ph of the water. Alkalinity and ph are best measured separately by titration and ph meter. However, if this is not possible, the following table shows a general relationship between alkalinity and ph. Caustic alkalinity, p alkalinity, and m alkalinity are these categories. Boiler alkalinity boiler alkalinity chemicals are used to increase the boiler water ph within the boiler water. P alkalinity is the measurement of hydroxide oh and carbonate ion co3 2 amount m alkanility is the measurement of hydroxide oh and bicarbonate hco3 and car. The recommended water tests are ph, malkalinity, total dissolved solids, iron and hardness.

The control of boiler water ph and alkalinity levels are important issue affecting the operation and maintenance of industrial boiler systems and steam raising. High boiler water alkalinity increases the potential for foaming, particularly in the presence of suspended matter. Carbonates and hydroxide may be significant when algal activity is high and in certain industrial water and wastewater, such as boiler water. In the high temperature and alkaline conditions normally maintained in a boiler, any soluble magnesium ions in the boiler water become extremely reactive with hydroxyl ions, which may be present in high concentrations in this type of environment. Acceptas high quality boiler water alkalinity builders and ph adjusters will help control ph levels in industrial boiler systems, hot water systems, and steam raising plant. If you decide to feed with hot water instead of cold water, the minerals in the water will come out of solution on the automatic water feeders seat, and that can cause a flood, especially if its a onepipesteam system. First, knowing the water source is important, whether it is from ponds, rivers, ground wells, or city water. Marine boiler water chemistry and treatment onboard february 12, 2018 august 21.

Boiler water alkalinity and ph needs to be maintained within limits else too high alkalinity leads to caustic corrosion and needs acid dosing. If you are in the market for an alkalinity increaser, the two most common are sodium bicarbonate nahco 3 and sodium carbonate na 2 co 3, more commonly known as. Alkalinity is defined as water capacity to neutralize acid, or the quantity of anions in water which can neutralize hydrogen cations. High alkalinity promotes boiler foaming and carryover and causes high amounts of boiler blowoff. Alkalinity up products are prevalent in the pool industry. Alkalinity is significant in the treatment processes for potable water and wastewater. Water treatment recommendations vary depending on the operating pressure of the boiler, the application steam or hot water, and other parameters. Boiler alkalinity boiler alkalinity products are used to increase the boiler water ph. Kintec 2264 is a high performance boiler water alkalinity builder scientifically formulated to maintain boiler feed water ph and alkalinity within a recommended operating range. Boiler water must contain a certain amount of causticity i. Alkalinity p, m and oh testing kit boilers cooling.

This video will cover information that you need to know about ph, alkalinity, and hardness, for your water treatment or water distribution exam. Free caustic is responsible for caustic corrosion in boiler system. What is a boiler feed water treatment system and how does. For the sake of simplicity, the presence of bicarbonate, carbonate and hydroxide contributes to the alkalinity of water. Chemworld stocks 25% and 50% of alkalinity solutions. All of the reagents are available to buy as spares separately using the drop down menu. Kintec 2264 aids the control of feed water ph and boiler system alkalinity. If the feed water does not meet these requirements it must. Jul 26, 2016 generally, natural water supplies have bicarbonate alkalinity, but no carbonate or hydroxide. Boiler chemicals are used to ensure proper boiler water quality in boilers. Alkalinity control is added to the boiler water to maintain an optimum alkalinity level to prevent corrosion. Feed water treatment to avoid corrosion makeup water to steam boilers should be treated with oxygen scavengers to avoid serious corrosion problems.

A common recommendation is to maintain boiler water at 8. Water is the most important liquid for sustained life because of its neutral ph of 7. If insufficient boiler water alkalinity is being maintained, magnesium can combine with phosphate. There can be too much conductivity in the feed water when there are too many dissolved solids. Palkalinity is the measurement of hydroxide oh and carbonate ion. Some of alkalinity is also required to provide optimum ph in feedwater to prevent corrosion in piping and equipment. Inhibitor requirements vary depending on the system.

The boiler water needs to be alkaline and not acidic. The below table is the total dissolved solids or tds, alkalinity, and hardness versus boiler pressure. Buy alkalinity titration kits at feedwater for testing alk m, alk p and alk oh by the method of dropper titration. Boiler alkalinity boiler chemical treatment products. But what is a boiler feed water treatment system and how does it work. Alkalinityp, m and oh ppm caco 3 testing kit rgpk002. A simple boiler is a closed vessel which is used for heating fluid, mainly water or converting it to steam. Feb 05, 2016 this feature is not available right now. What does the mean of m alkalinity and p alkalinity in boiler water. Although alkalinity is related to the basicity of an aqueous solution such as water, blood, etc. As can be seen, this would measure the amount of any. Boiler water, however, contains hydroxide and carbonate alkalinity, but no bicarbonate alkalinity.

The inhibition of embrittlement requires a definite ratio of nitrate to the caustic alkalinity present in the boiler water. Also covered are acids and bases, calcium carbonate. Corrosion related water chemistry corrosion and corrosion. Most industrial industrial boilers are made of mild steel or casting material. May 04, 2016 a boiler that makes up 4000 galday of water having 100 ppm of hardness, has a potential of accumulating over pounds of scale per year. If the feed water does not meet these requirements it must be pretreated to remove impurities. A typically recommended alkalinity rating is 140 700 ppm for boilers operating below 300 psi.